Improving the fill factor of N2200-based all polymer solar cells by introducing EPPDI as a solid additive

A cheap and commercially available small molecule (namely EPPDI) is introduced to the active layer of N2200-based all polymer solar cells as a solid additive. EPPDI at the optimal ratio can improve the D-A nano-scale morphology and reduce trap density of the active layer by filling morphological spaces. As a result, the photovoltaic performance of the resulting devices based on PF2:N2200 are increased from 6.28% to 7.03% with significantly enhanced fill factor. This work demonstrates a facile approach for improving the performance of all polymer solar cells.     

From enfant terrible to problem-solver? Tracing the competing discourse to explain blockchain-related technological diffusion

Since the inception of blockchain-related technologies over a decade ago, investors’ uptake of the technologies has grown rapidly. But even with the advancement in standing from conceptual beginnings to real-world experimentation, mainstream adoption of the technologies in either organizational or individual contexts has yet to eventuate. To resolve this paradox, we examine progression of the technologies’ diffusion instead, and in the process, seek to uncover the underlying dynamics of sentiments at play. Diffusion involves multiple actions by different parties, with social discourses via diverse media playing an essential role. In demonstrating the interplay of support to resistance via media framing and the diffusion of innovation theory, findings from our paper contribute to the technology adoption literature. Understanding resistant behavior toward a new technology area could help resolve potential issues that may arise. This would hopefully lead to better technological implementation outcomes in future.     

Electrical polarization and ionic conduction properties of β-tricalcium phosphate bioceramics with controlled vacancies by sodium ion substitution

With the aim to understand electric polarization mechanisms of β-tricalcium phosphate as an advanced biomaterial, Na ion-substituted β-Ca₃(PO₄)₂ (Na-β-TCPs) ceramics with controlled lattice vacancies were synthesized and structural refinement was performed by the Rietveld method. The Rietveld analysis revealed that Ca and vacancies at Ca(4) sites in the β-TCP structure decreased with an increase in Na substitution. Electrical measurements by the complex impedance method revealed that the conductivity and the activation energy calculated from Cole-Cole plots rapidly decreased to a constant value with an increase in Na substitution and decrease in vacancies. The thermally stimulated depolarization current (TSDC) curve of the electrically polarized Na-β-TCP showed one large peak at 530–610 °C. However, the accumulated charge decreased with an increase in Na ions and decrease in vacancies up to 2.37 mol%, after which it became constant. These results are consistent with the presumed formation of a dipole moment between aligned Ca²⁺ ions and their vacancies along the direction of the external polarization field applied at high temperature. We conclude that the large amount of stored charge in β-TCP caused by electrical polarization is due to the low site occupancy of calcium ions and vacancies at Ca(4) sites in the β-TCP structure, which is not the case for hydroxyapatite (HAp), as previously reported.     

Implication of Size-Controlled Graphite Nanosheets as Building Blocks for Thermal Conductive Three-Dimensional Framework Architecture of Nanocarbons

Preparation of three-dimensional (3D) networks has received significant attention as an effective approach for applications involving transport phenomena, such as thermal management materials, and several nanomaterials have been examined as potential building blocks of 3D networks for the improvement of heat conduction in polymer nanocomposites. For that purpose, nanocarbons such as graphene and graphite nanoplatelets have been spotlighted as suitable filler materials because of their excellent thermal conductivities (ca. 10²–10³ W·(m·K)^?1 along their lateral axes) and morphological merits. However, the implications of morphological features such as the lateral length and thickness of graphene or graphene-like materials have not yet been identified. In this study, a controlled dissociation of bulk graphite to graphite nanosheets (GNSs) using a low-cost, ecofriendly bead mill process was extensively examined and, when configured in a 3D framework architecture formation, the size-controlled GNSs demonstrated that the thermal conductivities of a 3D interconnected framework of GNSs and the corresponding polymer nanocomposite were intimately correlated with the size of the GNSs, thus demonstrating the successful preparation of an efficient thermal management material without highly sophisticated efforts. The capability of controlling the lateral size and thickness of the GNSs as well as the use of a 3D interconnected framework architecture should greatly assist the commercialization of high-quality graphene-based thermal management materials in a scalable production process.     

Generalized linear model based monitoring methods for high-yield processes

Emerge in technology brought well-organized manufacturing systems to produce high-quality items. Therefore, monitoring and control of products have become a challenging task for quality inspectors. From these highly efficient processes, produced items are mostly zero-defect and modeled based on zero-inflated distributions. The zero-inflated Poisson (ZIP) and zero-inflated Negative Binomial (ZINB) distributions are the most common distributions, used to model the high-yield and rare health-related processes. Therefore, data-based control charts under ZIP and ZINB distributions (i.e., Y-ZIP and Y-ZINB) are proposed for the monitoring of high-quality processes. Usually, with the defect counts, few covariates are also measured in the process, and the generalized linear model based on the ZIP and ZINB distributions are used to estimate their parameters. In this study, we have designed monitoring structures (i.e., PR-ZIP and PR-ZINB) based on the ZIP and ZINB regression models which will provide the monitoring of defect counts by accounting the single covariate. Further, proposed model-based charts are compared with the existing data-based charts. The simulation study is designed to access the performance of monitoring methods in terms of run length properties and a case study on the number of flight delays between Atlanta and Orlando during 2012–2014 is also provided to highlight the importance of the stated research.     

15209综采工作面端面破碎机理及控制

15209工作面回采期间端面处出现破碎、冒落现象,造成液压支架初撑力、工作阻力降低,威胁着工作面安全高效回采。通过技术研究,分析了15209工作面端面破碎机理,提出了"施工梯形锚索吊棚+注浆加固+走向掏槽搭梁"联合控制措施。实际应用表明端面破碎、煤壁片帮现象得到控制,工作面回采速度提高至7.5m/d,取得了显著应用成效。     

车辆高速避让路径跟踪控制策略

建立车辆动力学模型,研究车辆在高速避让工况下的路径跟踪控制策略。基于自抗扰控制设计车辆横摆角速度以及道路曲率2种不同的路径跟踪控制器;设计基于车辆偏航位移和偏航角度加权的线性二次最优控制器;对3种控制器控制效果进行仿真验证,分析路径跟踪侧向位移误差、侧向加速度、前轮转向角以及偏航角度变化。越野车实车测试结果表明,路径跟踪控制策略正确。     

HACCP在浓香菜籽油生产中的应用

为了保障浓香菜籽油的产品质量安全,采用HACCP体系对浓香菜籽油生产全过程进行生物、物理、化学的危害分析,确定关键控制点,制定预防措施,并对生产环节进行有效监控,制定纠偏措施,做好记录管理,为浓香菜籽油的安全生产提供借鉴。     

焦炉前反馈热工控制系统运行实践

焦炉生产是典型的大惯性、非线性、时变快的复杂系统，以“火落温度”为基础的焦炉前反馈热工控制系统，通过立火道温度自动测量与人工测温相关性分析、粗煤气温度测量与火落判断、标准温度的优化等运行实践，达到了自动火落时间判断、标准温度指导、加热和燃烧优化、高低温炉号判别等目的，对于稳定炉温、降低回炉煤气消耗、提高焦炭质量以及推进焦化企业技术进步具有重要意义。